The purpose of the study aims to discuss the effects of employees’ job stress, job burnout and service quality among international tourist hotels employees. The study further examines the moderating role of work value between the associations between job stress and job burnout as well as job burnout and service quality. The employees’ service quality was evaluated by their direct supervisors. Employees who have worked in the international tourist hotels for more than one year were invited to participate in the study. By using convenience sampling, the structured questionnaire was distributed to 550 supervisor-subordinate dyads and a total of 370 valid dyads data was returned to the research institute. The results of the study suggested the significantly positive relationships between job stress and job burnout as well as job burnout and service quality. Additionally, the full mediating role of job burnout in the relationship between job stress and service quality was also identified. When employees’ work values are high than low, the job stress has a less significant impact on job burnout. The negative relationship between job burnout and service quality is significantly buffered when employees’ work values are high than low.