This paper aims to improve the coupling efficiency of directional couplers in an asymmetrical S-bend configuration. The paper designs a straight waveguide and an S-bend waveguide with a fixed curvature radius. By changing the width of the straight waveguide to match the mode index of the curved waveguide, phase matching conditions can be achieved. The directional coupler is composed of two mirrored S-bends, and when the mode indices of the two waveguides are identical, the directional coupler can achieve 100% synchronous coupling efficiency.