To provide market proof of green environment, this study analyzed the relationship between users’ perceived benefits of green office buildings and their willing to pay in Taiwan using questionnaires. Empirical results show that most office users have a positive evaluation on green buildings and would pay more for the rents. It indicates that using substitute market data to analyze green values is an effective path, especially for areas where there are fewer transactions. In terms of improving the analysis methods, this study deals with the possible problems related to synergistic effects of green buildings and reasonably reflects the perceived value of green buildings to prevent overestimation. We suggests that property developers, landowners, landlords, and tenants can be more actively involved in the green building development or become genuine users and create a diverse and mutually beneficial environment. Simultaneously, to ensure a fair and objective demonstration of the benefits of green buildings, appraisers should regard such information as an important factor in valuations. The government will continue to play a role in the promotion of green buildings and providing information. Follow-up studies can target different green building grading systems and perform comparative analysis.