Synaesthesia as a literature rhetoric device has received much attention from scholars. Cognitive linguistics studies synaesthesia at the cognitive level and argues that synaesthesia is a conceptual metaphor as an important cognitive method. Multimodal Metaphor, which is a heated topic in todays metaphor studies, offers a new perspective in the study of synaesthesia as a literature rhetoric device. Both synaesthesia and multimodal metaphor can be considered from the perspectives of language rhetoric and cognitive mechanism. This paper discusses the relation among synaesthesia, metaphor and multimodal metaphor by reviewing previous literature, and some examples are in-detail introduced. Metaphor in the cognitive scale, or conceptual metaphor, whose nature is to provide people the mechanism to understand or experience one item through the other, can be reflected in many ways of language rhetoric. Multimodal metaphor has the same property despite more modalities are involved. Both synaesthesia or multimodal metaphor can be found in language rhetoric, arts creation, aesthetic activities and many other interfaces of daily life since they are regarded as a cognitive mechanism of human beings.