This study investigated Taiwanese junior high school students’ learning experiences in an affective education curriculum, focusing on the “myths of romantic love”. A teaching experiment was conducted to examine the relationship between students’ epistemic emotions and their use of critical thinking strategies. The study also examined whether students’ value appraisals of the course moderated the relationship between epistemic emotions and critical thinking strategies. Specifically, the study first tested the indirect effects of surprise on critical thinking strategies– positively through curiosity and negatively through confusion, and then analyzed whether these mediating effects were conditioned by students’ perceived value of the course. A total of 205 eighth-grade students from a metropolitan city in southern Taiwan participated in the study. Structural equation modeling was used to examine both mediation and conditional indirect effects. The results showed that during the lesson: (1) surprise had both positive and negative indirect effects on students’ use of critical thinking strategies— positively through curiosity and negatively through confusion; and (2) value appraisal moderated the indirect effect of surprise on critical thinking via confusion— this negative pathway was significant only among students who rated the course value very low (i.e., a score of 1). Based on these findings, the study offers instructional implications for affective education in junior high schools and contributes to the growing body of research on epistemic emotions in domain-specific learning contexts.