We analyze the board structure and corporate social responsibility (CSR) issuance of listed computer and consumer electronics manufacturing and semiconductor firms in Taiwan by the sub-sample analysis before- and after- year 2012. After the intensified corporate governance plan for upgrading the international ranking among Asian countries, only the proportion of independent directors is statistically different between the two sub-periods. We infer that the different proportions of independent directors might be directly caused by the mandated independent director regulation of listed firms. Besides, we further divide our sample firms into two types (CEOs and chairmen with or without religious belief). The characteristic of board structure and the willingness of CSR issuance are statistically different between the religious belief sub-groups. Finally, this study adopts the logit model for the determinants of sample firms’ CSR issuances from board structure. We provide the evidence that the proportion of busy director (board structure) has a significantly and positively impact on the willingness of next year CSR issuances. Due to the compulsory CSR issuance with capital threshold enacted in year 2014, we exclude the sample firms with the compulsory regulation or religious belief of CEOs and Chairmen as robustness checks. Corporate social responsibility issuance is critical for enhancing the quality of corporate governance and connection of Taiwanese listed firms with international capital markets. The findings here not only provide some policy implications but also investment suggestions for institutional investors either.