In this research, a positive thinking mobile learning system, which consist of an online learning system based on the Moodle platform and a mobile device with the augmented reality system is designed. This study focuses on the learning effect for three group’s college students. We adopt the one group pretest-posttest experimental methodology to explore the learning effectiveness of using the positive thinking learning in coping learning disturbances of three group’s students with learning disturbances. We also study satisfaction issue of using the positive thinking mobile learning system function. The experimental group takes positive thinking mobile learning system by self-directive learning. An online learning system is also used to allow students to access multimedia teaching materials at any time. The problem-oriented group cooperative learning and counseling mechanism were using to conduct real-time learning for learning disturbances within semester. The statistic results as fellow: 1. The positive thinking mobile learning system designed by this study can promote the three experimental group college students’ resilience and learning effect in coping learning disturbances. And these three experimental groups have significant differences between pretest and posttest in coping learning disturbances and resilience; 2. The “teaching potential” is the most satisfaction dimension of the positive thinking mobile learning system by the three experimental group college students.